304 capillary tube Nanocomposites E Thehiloe ho Tungsten Oxide/Fullerene e le Electrocatalysts le Inhibitors of Parasitic VO2+/VO2+ Reactions in Mixed Acids

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Sebopeho sa Lik'hemik'hale sa Coil Tube ea Stainless 304

304 Stainless Steel Coil Tube ke mofuta oa alloy chromium-nickel alloy.Ho ea ka Stainless Steel 304 Coil Tube Manufacturer, karolo e ka sehloohong ho eona ke Cr (17% -19%), le Ni (8% -10.5%).E le ho ntlafatsa khanyetso ea eona ho corrosion, ho na le chelete e nyane ea Mn (2%) le Si (0.75%).

Lisebelisoa tsa Mechanical tsa Coil Tube ea Stainless 304

Thepa ea mochini oa 304 coil coil tube ke e latelang:

• Matla a khoheli: ≥515MPa
• Matla a ho hlahisa: ≥205MPa
• Elongation: ≥30%

Lits'ebeliso le Ts'ebeliso ea Ts'ebetso ea Ts'ebetso ea Ts'epi ea 304 Coil Tube

Litsenyehelo tse batlang li le holimo tsa li-betri tsa vanadium redox flow (VRFBs) li fokotsa tšebeliso ea tsona e atileng.The kinetics of electrochemical reactions e tlameha ho ntlafatsoa e le ho eketsa matla a matla le matla a matla a VRFB, kahoo ho fokotsa litšenyehelo tsa kWh tsa VRFB.Mosebetsing ona, hydrothermally synthesized hydrated tungsten oxide (HWO) nanoparticles, C76 le C76 / HWO, li ile tsa kenngoa ka li-electrode tsa lesela la carbon 'me tsa lekoa e le li-electrocatalysts bakeng sa VO2 +/VO2+ redox reaction.Field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier ea infrared fetola Spectroscopy (FTIR) le litekanyo tsa angle angle.Ho fumanoe hore tlatsetso ea C76 fullerene ho HWO e ka ntlafatsa kinetics ea electrode mabapi le VO2 +/VO2 + redox reaction ka ho eketsa conductivity le ho fana ka lihlopha tse sebetsang tse nang le oksijene holim'a eona.Motsoako oa HWO/C76 (50 wt% C76) o ipakile e le oona o loketseng karabelo ea VO2+/VO2+ ka ΔEp ea 176 mV ha e bapisoa le 365 mV bakeng sa lesela la khabone le sa sebetsoang (UCC).Ho phaella moo, motsoako oa HWO / C76 o bontšitse thibelo e kholo ea ho fetoha ha likokoana-hloko tsa chlorine ka lebaka la lihlopha tse sebetsang tsa W-OH.
Ts'ebetso e matla ea batho le phetoho e potlakileng ea indasteri e lebisitse tlhokeho e phahameng e ke keng ea thijoa ea motlakase, e ntseng e hola ka hoo e ka bang 3% ka selemo1.Ka lilemo tse mashome, tšebeliso e pharalletseng ea libeso e le mohloli oa matla e lebisitse ho ntšoeng ha likhase tse futhumatsang lefatše, ho lebisang ho futhumaleng ha lefatše, tšilafalo ea metsi le moea, e leng ho sokelang tikoloho eohle.Ka lebaka leo, ka 2050 karolo ea matla a hloekileng a tsosolositsoeng le matla a letsatsi a reretsoe ho fihla ho 75% ea kakaretso ea motlakase1.Leha ho le joalo, ha tlhahiso ea matla a tsosolositsoeng e feta 20% ea kakaretso ea tlhahiso ea motlakase, marang-rang a fetoha a sa tsitsang 1. Tsoelo-pele ea mekhoa e sebetsang ea ho boloka matla e bohlokoa bakeng sa phetoho ena, kaha ba tlameha ho boloka motlakase o feteletseng le ho leka-lekanya phepelo le tlhokahalo.
Har'a lisebelisoa tsohle tsa polokelo ea matla tse kang hybrid vanadium redox flow batterys2, li-betri tsohle tsa vanadium redox flow (VRFBs) ke tse tsoetseng pele ka ho fetisisa ka lebaka la melemo ea tsona e mengata3 'me li nkoa e le tharollo e molemo ka ho fetisisa bakeng sa polokelo ea nako e telele ea matla (~ lilemo tse 30).Tšebeliso ea mehloli ea matla a ka nchafatsoang4.Sena se bakoa ke karohano ea matla le matla a matla, karabelo e potlakileng, bophelo bo bolelele le litšenyehelo tse batlang li le tlase tsa selemo le selemo tsa $ 65 / kWh ha li bapisoa le $ 93-140 / kWh bakeng sa Li-ion le libeteri tsa lead-acid le 279-420 USD / kWh./kWh libeteri ka ho latellana 4.
Leha ho le joalo, khoebo ea bona e atileng e ntse e tsoela pele ho sitisoa ke litšenyehelo tse phahameng tsa lichelete tsa sistimi, haholoholo ka lebaka la li-betri packs4,5.Kahoo, ho ntlafatsa ts'ebetso ea betri ka ho eketsa kinetics ea likarolo tse peli tsa lisele tse peli ho ka fokotsa boholo ba betri mme ka hona ho fokotsa litšenyehelo.Ka hona, ho fetisetsoa ha elektronike ka potlako sebakeng sa electrode hoa hlokahala, ho itšetlehile ka moralo, sebopeho le sebopeho sa electrode, e lokelang ho ntlafatsoa ka hloko.Le hoja li-electrode tse entsoeng ka carbon li na le botsitso bo botle ba lik'hemik'hale le electrochemical le motlakase o motle oa motlakase, haeba o sa phekoloe, kinetics ea bona e tla lieha ka lebaka la ho se be teng ha lihlopha tse sebetsang tsa oksijene le hydrophilicity7,8.Ka hona, li-electrocatalyst tse fapa-fapaneng li kopantsoe le li-electrode tsa carbon, haholo-holo li-carbon nanostructures le li-oxide tsa tšepe, ho ntlafatsa kinetics ea li-electrode ka bobeli, kahoo ho eketsa kinetics ea li-electrode tsa VRFB.
Ho sebelisitsoe lintho tse ngata tsa carbon, tse kang carbon paper9, carbon nanotubes10,11,12,13, graphene-based nanostructures14,15,16,17, carbon nanofibers18 le tse ling19,20,21,22,23, ntle le lelapa la fullerene. .Thutong ea rona e fetileng ka C76, re tlalehile ka lekhetlo la pele ts'ebetso e babatsehang ea electrocatalytic ea fullerene ena ho ea ho VO2 +/VO2 +, ha e bapisoa le lesela la carbon le nang le mocheso le sa phekoloang, ho hanyetsa phetisetso ea tefiso ho fokotsehile ka 99.5% le 97% 24.Ts'ebetso e matla ea lisebelisoa tsa khabone bakeng sa karabelo ea VO2+/VO2+ ha e bapisoa le C76 e bonts'oa ho Lethathamo la S1.Ka lehlakoreng le leng, li-oxide tse ngata tsa tšepe tse kang CeO225, ZrO226, MoO327, NiO28, SnO229, Cr2O330 le WO331, 32, 33, 34, 35, 36, 37, 38 li sebelisoa ka lebaka la ho eketseha ha tsona ho metsi le oksijene e ngata.lihlopha.Letlapa la S2 le bonts'a ts'ebetso e matla ea li-oxide tsena tsa tšepe karabelong ea VO2+/VO2+.WO3 e 'nile ea sebelisoa mesebetsing e mengata ka lebaka la theko e tlaase, botsitso bo phahameng mecheng ea litaba tsa acidic, le ts'ebetso e phahameng ea catalytic31,32,33,34,35,36,37,38.Leha ho le joalo, WO3 e bontšitse ntlafatso e nyenyane ho cathode kinetics.Ho ntlafatsa conductivity ea WO3, phello ea ho sebelisa tungsten oxide e fokotsehileng (W18O49) mosebetsing o motle oa electrode e ile ea lekoa38.Hydrated tungsten oxide (HWO) ha e e-s'o ka e lekoa lits'ebetsong tsa VRFB, le hoja e bontšitse ts'ebetso e phahameng ho li-supercapacitor applications ka lebaka la phallo e potlakileng ea cation ha e bapisoa le anhydrous WOx39,40.Moloko oa boraro oa betri ea phallo ea "vanadium redox" e sebelisa electrolyte e tsoakiloeng ea asiti e entsoeng ka HCl le H2SO4 ho ntlafatsa ts'ebetso ea betri le ho ntlafatsa ho qhibiliha le botsitso ba li-ion tsa vanadium ka electrolyte.Leha ho le joalo, karabelo ea phetoho ea chlorine ea parasitic e fetohile e 'ngoe ea mathata a moloko oa boraro, kahoo ho fumana litsela tsa ho hatella karabelo ea tlhahlobo ea chlorine e fetohile mosebetsi oa lihlopha tse' maloa tsa lipatlisiso.
Mona, liteko tsa karabelo tsa VO2+/VO2+ li ile tsa etsoa ho li-composites tsa HWO/C76 tse kentsoeng li-electrode tsa lesela la k'habone e le ho fumana ho leka-lekana pakeng tsa conductivity ea motlakase ea metsoako le redox reaction kinetics holim'a electrode ha e ntse e hatella parasitic chlorine deposition.karabelo (KVR).Hydrated tungsten oxide (HWO) nanoparticles e entsoe ka mokhoa o bonolo oa hydrothermal.Liteko li ile tsa etsoa ka motsoako oa acid e electrolyte (H2SO4/HCl) ho etsisa moloko oa boraro oa VRFB (G3) bakeng sa boiketlo le ho batlisisa phello ea HWO ho parasitic chlorine evolution reaction42.
Vanadium (IV) sulfate oxide hydrate (VOSO4, 99.9%, Alfa-Aeser), sulfuric acid (H2SO4), hydrochloric acid (HCl), dimethylformamide (DMF, Sigma-Aldrich), polyvinylidene fluoride (PVDF, Sigma-Aldrich), sodium Tungsten oxide dihydrate (Na2WO4, 99%, Sigma-Aldrich) le hydrophilic carbon cloth ELAT (Fuel Cell Store) li sebelisitsoe thutong ena.
Hydrated tungsten oxide (HWO) e ile ea lokisoa ke karabelo ea hydrothermal moo 2 g ea letsoai la Na2WO4 e ileng ea qhibiliha ka 12 ml ea HO ho fihlela ho fumanoa tharollo e se nang 'mala, ebe 12 ml ea 2 M HCl e eketsoa ka tsela e fokolang ho fihlela ho emisoa ha mosehla o khanyang. e fumanoe.ho emisoa.Karabelo ea hydrothermal e ile ea etsoa ka Teflon e koahetsoeng ka tšepe e sa hloekang autoclave ka ontong ea 180 ºC ka lihora tse 3.Masala a ne a bokelloa ka ho hloekisa, a hlatsuoa ka makhetlo a 3 ka ethanol le metsi, a omisitsoe ka ontong ka 70 ° C bakeng sa ~ 3 h, ebe o fatše ho fumana phofo ea HWO e putsoa.
Li-electrode tsa lesela la carbon (CCTs) tse fumanoeng (tse sa tšoaroeng) li ne li sebelisoa ka mokhoa oo li fumanoeng ka tsona kapa li tlas'a phekolo ea mocheso ka sebōpi sa tube ka 450 ° C bakeng sa 10 h ka mocheso oa mocheso oa 15 ° C / min moeeng ho ea. fumana tšoaroa UCC (TCC), s Ho tšoana le mosebetsi o fetileng 24. UCC le TCC li ile tsa khaoloa ka li-electrode tse ka bang 1.5 cm ka bophara le bolelele ba 7 cm.Ho emisoa ha C76, HWO, HWO-10% C76, HWO-30% C76 le HWO-50% C76 ho ile ha lokisetsoa ka ho eketsa 20 mg ea phofo ea thepa e sebetsang le 10 wt% (~ 2.22 mg) ea PVDF binder ho ~ 1 ml ea DMF e lokiselitsoe le ho sonicated bakeng sa hora e le 1 ho ntlafatsa ho tšoana.Joale 2 mg ea metsoako ea C76, HWO le HWO-C76 e sebelisitsoe hoo e ka bang 1.5 cm2 ea sebaka sa UCC se sebetsang sa electrode.Li-catalyst tsohle li ne li laeloa ho li-electrode tsa UCC 'me TCC e ne e sebelisetsoa merero ea ho bapisa feela, kaha mosebetsi oa rona o fetileng o bontšitse hore phekolo ea mocheso ha e hlokehe 24.Ho rarolla maikutlo ho ile ha finyelloa ka ho hlatsoa 100 µl ea ho emisoa (moroalo 2 mg) bakeng sa ho tšoana ho hoholo.Ebe li-electrode tsohle li omisoa ka ontong bosiu bo le bong ka 60 ° C.Li-electrode li lekantsoe pele le ka morao ho etsa bonnete ba hore stock loading e nepahetseng.E le ho ba le sebaka se itseng sa geometri (~ 1.5 cm2) le ho thibela ho phahama ha vanadium electrolyte ho li-electrode ka lebaka la phello ea capillary, ho ne ho sebelisoa lesela le tšesaane la parafine holim'a thepa e sebetsang.
Ho ile ha sebelisoa maekerosekoupo ea elektronike e hlahang tšimong (FESEM, Zeiss SEM Ultra 60.5 kV) ho hlokomela morphology ea holim'a HWO.Setšoantšo sa X-ray se qhalakanyang matla se nang le Feii8SEM (EDX, Zeiss AG) se ile sa sebelisoa ho etsa 'mapa oa likarolo tsa HWO-50% C76 ho li-electrode tsa UCC.Maekerosekoupo ea elektronike ea phetisetso e phahameng (HR-TEM, JOEL JEM-2100) e sebetsang ka lebelo le potlakileng la 200 kV e ile ea sebelisoa ho fumana litšoantšo tse nang le qeto e phahameng le mehele ea diffraction ea likaroloana tsa HWO.Sebelisa software ea Crystallographic Tool Box (CrysTBox) ho sekaseka mehele ea phallo ea HWO u sebelisa tšebetso ea ringGUI le ho bapisa liphetho le mefuta ea XRD.Sebopeho le graphitization ea UCC le TCC li ile tsa khethoa ke X-ray diffraction (XRD) ka tekanyo ea scan ea 2.4 ° / min ho tloha 5 ° ho ea 70 ° le Cu Kα (λ = 1.54060 Å) ho sebelisa Panalytical X-ray diffractometer.(Mohlala 3600).XRD e bonts'a sebopeho sa kristale le mekhahlelo ea HWO.Software ea PANalytical X'Pert HighScore e ile ea sebelisoa ho bapisa litlhōrō tsa HWO le limmapa tsa tungsten oxide tse fumanehang polokelong ea polokelo45.Bapisa liphetho tsa HWO le liphetho tsa TEM.Sebopeho sa lik'hemik'hale le boemo ba lisampole tsa HWO li ile tsa khethoa ke X-ray photoelectron spectroscopy (XPS, ESCALAB 250Xi, ThermoScientific).Software ea CASA-XPS (v 2.3.15) e ile ea sebelisoa bakeng sa tlhōrō ea ts'ebetso le tlhahlobo ea data.Fourier transform infrared spectroscopy (FTIR, ho sebelisoa litekanyo tsa sehlopha sa Perkin Elmer KBr FTIR spectrometer) li ile tsa etsoa ho fumana lihlopha tse sebetsang ka holimo tsa HWO le HWO-50% C76.Bapisa liphetho le liphetho tsa XPS.Litekanyo tsa angle angle (KRUSS DSA25) li ne li boetse li sebelisetsoa ho khetholla ho ba metsi ha li-electrode.
Bakeng sa litekanyo tsohle tsa electrochemical, ho ile ha sebelisoa setsi sa mosebetsi sa Biologic SP 300.Cyclic voltammetry (CV) le electrochemical impedance spectroscopy (EIS) li ile tsa sebelisoa ho ithuta electrode kinetics ea VO2 +/VO2+ redox reaction le phello ea reagent diffusion (VOSO4 (VO2 +)) ka tekanyo ea ho itšoara.Litheknoloji tsena ka bobeli li sebelisa sele ea electrode e meraro e nang le motsoako oa electrolyte oa 0.1 M VOSO4 (V4+) o qhibilihisitsoeng ka 1 M H2SO4 + 1 M HCl (asiti e tsoakiloeng).Lintlha tsohle tsa electrochemical tse hlahisitsoeng li lokisitsoe IR.Ho ile ha sebelisoa k'halomele ea "saturated calomel electrode" (SCE) le "platinum" (Pt) "electrode" ea "referense" le "counter electrode", ka ho latellana.Bakeng sa CV, litekanyetso tsa scan (ν) tsa 5, 20, le 50 mV/s li ile tsa sebelisoa fensetereng e ka bang teng (0–1) V ha e bapisoa le SCE bakeng sa VO2+/VO2+, ebe e lokisoa sekaleng sa SHE ho rera (VSCE = 0.242 V e amanang le HSE) .Ho batlisisa ka ho bolokoa ha tšebetso ea li-electrode, ho ile ha etsoa recycle ea CV ho UCC, TCC, UCC-C76, UCC-HWO le UCC-HWO-50% C76 ho ν e lekanang le 5 mV/s.Bakeng sa litekanyo tsa EIS bakeng sa karabelo ea VO2 +/VO2+ redox, maqhubu a mangata a 0.01-105 Hz le tšitiso e bulehileng ea potoloho (OCV) ea 10 mV e ile ea sebelisoa.Teko e 'ngoe le e' ngoe e phetoa ka makhetlo a 2-3 ho netefatsa hore liphetho li lumellana.Mefuta e sa tšoaneng ea litekanyetso (k0) e fumanoe ka mokhoa oa Nicholson46,47.
Hydrated tungsten oxide (HVO) e entsoe ka katleho ka mokhoa oa hydrothermal.Setšoantšo sa SEM ka feiga.1a e bonts'a hore HWO e kentsoeng e na le lihlopha tsa li-nanoparticles tse nang le boholo ba likaroloana tsa 25-50 nm.
Mokhoa oa X-ray diffraction oa HWO o bontša litlhōrō (001) le (002) ho ~ 23.5 ° le ~ 47.5 °, ka ho latellana, e leng tšobotsi ea nonstoichiometric WO2.63 (W32O84) (PDF 077-0810, a = 21.4 Å, b = 17.8 Å, c = 3.8 Å, α = β = γ = 90 °), e lumellanang le 'mala oa eona o moputsoa o bonahalang (setšoantšo sa 1b) 48,49.Litlhōrō tse ling tse ka bang 20.5°, 27.1°, 28.1°, 30.8°, 35.7°, 36.7° le 52.7° li ho (140), (620), (350), (720), (740), (560).le (970) lifofane tsa diffraction, ka ho latellana, 49 orthorhombic WO2.63.Songara et al.43 e sebelisitse mokhoa o tšoanang oa maiketsetso ho fumana sehlahisoa se tšoeu, se neng se bakoa ke boteng ba WO3 (H2O) 0.333.Leha ho le joalo, mosebetsing ona, ka lebaka la maemo a fapaneng, ho ile ha fumanoa sehlahisoa se seputsoa-bohlooho, se bontšang ho ba teng ha WO3 (H2O) 0.333 (PDF 087-1203, a = 7.3 Å, b = 12.5 Å, c = 7.7) ho Å , α = β = γ = 90 °) le mofuta o fokotsehileng oa tungsten oxide.Tlhahlobo ea semiquantitative ka software ea X'Pert HighScore e bontšitse 26% WO3 (H2O) 0.333: 74% W32O84.Kaha W32O84 e na le W6+ le W4+ (1.67:1 W6+:W4+), likhakanyo tse hakanyetsoang tsa W6+ le W4+ li ka ba 72% W6+ le 28% W4+, ka ho latellana.Litšoantšo tsa SEM, ponahalo ea XPS ea 1-ea bobeli boemong ba nucleus, litšoantšo tsa TEM, FTIR spectra le Raman spectra ea likaroloana tsa C76 li hlahisitsoe pampiring ea rona e fetileng24.Ho ea ka Kawada et al.50,51, mohlala oa X-ray diffraction oa C76 o bontša sebopeho sa monoclinic sa FCC ka mor'a ho tlosoa ha toluene.
Litšoantšo tsa SEM ka feiga.2a le b li bonts'a ho beoa ka katleho ha HWO le HWO-50% C76 le lipakeng tsa likhoele tsa khabone tsa li-electrode tsa UCC.'Mapa oa mantlha oa tungsten, khabone le oksijene setšoantšong sa SEM setšoantšong sa 2c se bonts'oa feiga.2d–f e bontšang hore tungsten le carbon li tsoakane ka mokhoa o ts'oanang (ho bonts'a kabo e tšoanang) holim'a sebaka sa electrode 'me motsoako ha o behe ka ho lekana.ka lebaka la mofuta wa mokgoa wa pula.
Litšoantšo tsa SEM tsa likaroloana tsa HWO tse kentsoeng (a) le likaroloana tsa HWO-C76 (b).'Mapa oa EDX o kentsoeng ho HWO-C76 ho UCC ho sebelisoa sebaka se setšoantšong (c) se bonts'a kabo ea tungsten (d), carbon (e), le oxygen (f) sampuling.
HR-TEM e ne e sebelisetsoa litšoantšo tse phahameng tse holisang le tlhahisoleseling ea crystallographic (Setšoantšo sa 3).HWO e bonts'a morphology ea nanocube joalo ka ha e bonts'itsoe ho Setšoantšo sa 3a le ka ho hlaka ho Setšoantšo sa 3b.Ka ho holisa nanocube bakeng sa diffraction ea sebaka se khethiloeng, sebopeho sa grating le lifofane tsa diffraction tse khotsofatsang molao oa Bragg li ka bonoa joalokaha ho bontšoa ho Setšoantšo sa 3c, se tiisang crystallinity ea thepa.Karolong e ka tlase ho Setšoantšo sa 3c e bonts'a sebaka sa d 3.3 Å se lumellanang le (022) le (620) lifofane tsa diffraction ho WO3 (H2O) 0.333 le W32O84, 43, 44, 49 mekhahlelo, ka ho latellana.Sena se lumellana le tlhahlobo e ka holimo ea XRD (setšoantšo sa 1b) kaha sebaka sa sefofane sa grating se hlokometsoeng d (setšoantšo sa 3c) se lumellana le tlhōrō e matla ka ho fetisisa ea XRD ho sampuli ea HWO.Mehele ea mohlala e boetse e bontšoa ka feiga.3d, moo selikalikoe se seng le se seng se lumellanang le sefofane se arohaneng.Lifofane tsa WO3 (H2O) 0.333 le W32O84 li na le mebala e tšoeu le e putsoa, ​​ka ho latellana, 'me litlhōrō tsa tsona tsa XRD tse tsamaellanang le tsona li bontšoa setšoantšong sa 1b.Lesale la pele le bontšitsoeng pateroneng ea lesale le lumellana le tlhoro ea pele e tšoailoeng ka mokhoa oa x-ray oa sefofane sa (022) kapa (620) sa diffraction.Ho tloha (022) ho ea ho (402) mehele, d-distances tsa 3.30, 3.17, 2.38, 1.93, le 1.69 Å li fumanoe, tse lumellanang le litekanyetso tsa XRD tsa 3.30, 3.17, 2 .45, 1.63 le 1.63.Å, 44, 45, ka ho latellana.
(a) Setšoantšo sa HR-TEM sa HWO, (b) se bontša setšoantšo se holisitsoeng.Litšoantšo tsa lifofane tsa grating li bontšoa ho (c), 'me inset (c) e bontša setšoantšo se atolositsoeng sa lifofane le nako ea d 0.33 nm e lumellanang le lifofane tsa (002) le (620).(d) Mohlala oa lesale oa HWO o bontšang lifofane tse amanang le mekhahlelo ea WO3 (H2O) 0.333 (e tšoeu) le W32O84 (e putsoa).
Tlhahlobo ea XPS e ile ea etsoa ho fumana hore na k'hemistri e holim'a metsi le boemo ba oxidation ea tungsten (Lipalo S1 le 4).Sekhahla sa tlhahlobo ea XPS e pharaletseng ea HWO e entsoeng e bontšoa ho Feiga.S1, e bontšang boteng ba tungsten.XPS e tšesaane-scan spectra ea maemo a mantlha a W 4f le O 1s e bonts'itsoe ho Feiga.4a le b, ka ho latellana.Maqhubu a W 4f a arotsoe ka makhetlo a mabeli a spin-orbit a tsamaisanang le matla a tlamang a boemo ba oxidation W. Litlhōrō tsa W 4f5/2 le W 4f7/2 ka matla a tlamang a 37.8 le 35.6 eV ke a W6+, 'me litlhōrō tsa W 4f5/2 le W 4f7/2 4f5/2 le W 4f7/2 ho 36.6 le 34.9 eV ke litšobotsi tsa boemo ba W4+, ka ho latellana.Ho ba teng ha boemo ba oxidation (W4 +) ho tiisa hape ho thehoa ha WO2.63 e seng stoichiometric, ha ho ba teng ha W6 + ho bontša stoichiometric WO3 ka lebaka la WO3 (H2O) 0.333.Lintlha tse kentsoeng li bonts'itse hore liperesente tsa athomo tsa W6+ le W4+ e ne e le 85% le 15%, ka ho latellana, tse neng li batla li le haufi le boleng bo hakantsoeng ho data ea XRD, ha ho fanoa ka phapang lipakeng tsa mahlale ana a mabeli.Mekhoa ena ka bobeli e fana ka tlhaiso-leseling e ngata ka nepo e tlase, haholo XRD.Ntle le moo, mekhoa ena e 'meli e sekaseka likarolo tse fapaneng tsa lisebelisoa hobane XRD ke mokhoa o mongata ha XPS e le mokhoa o holimo o atamelang li-nanometer tse' maloa feela.Sekhahla sa O 1 se arohana ka litlhōrō tse peli ho 533 (22.2%) le 530.4 eV (77.8%).Ea pele e lumellana le OH, 'me ea bobeli e lumellana le litlamo tsa oksijene letšeng ho WO.Ho ba teng ha lihlopha tse sebetsang tsa OH ho lumellana le thepa ea hydration ea HWO.
Tlhahlobo ea FTIR e boetse e etsoa lisampoleng tsena tse peli ho hlahloba boteng ba lihlopha tse sebetsang le limolek'hule tsa metsi tse hokahaneng ka har'a sebopeho sa HWO se nang le metsi.Liphetho li bontša hore mohlala oa HWO-50% C76 le liphetho tsa FT-IR HWO li shebahala li tšoana ka lebaka la boteng ba HWO, empa matla a litlhōrō a fapane ka lebaka la mefuta e sa tšoaneng ea sampuli e sebelisoang nakong ea ho lokisetsa tlhahlobo (Setšoantšo sa 5a). ).HWO-50% C76 Litlhōrō tsohle tse tletseng fullerene 24 li bontšoa ntle le tungsten oxide tlhoro.E qaqileng ka feiga.5a e bonts'a hore lisampole ka bobeli li bonts'a sehlopha se matla haholo se sephara ho ~ 710 / cm, se hlahisoang ke ho sisinyeha ho otlollang ha OWO ka sebopeho sa lattice sa HWO, le lehetla le matla ho ~ 840 / cm, le amahanngoa le WO.sehlopha se bohale ho ~ 1610 / cm se amana le ho thothomela ha OH, 'me sehlopha se pharaletseng sa ho monya ho ~ 3400 / cm se amana le ho thothomela ho otlolohileng ha OH sehlopheng sa hydroxyl43.Liphello tsena li lumellana le sebopeho sa XPS setšoantšong sa 4b, moo sehlopha se sebetsang sa WO se ka fanang ka libaka tse sebetsang bakeng sa karabelo ea VO2 +/VO2 +.
Tlhahlobo ea FTIR ea HWO le HWO-50% C76 (a) e bontšang lihlopha tse sebetsang le litekanyo tsa angle angle (b, c).
Sehlopha sa OH se ka boela sa kenya letsoho karabelo ea VO2 +/VO2+, kahoo sa eketsa hydrophilicity ea electrode, kahoo se khothalletsa ho hasana le litekanyetso tsa phetisetso ea elektronike.Mohlala oa HWO-50% C76 o bonts'a tlhōrō e eketsehileng ea C76 joalokaha ho bontšitsoe setšoantšong.Litlhōrō ho ~ 2905, 2375, 1705, 1607, le 1445 cm3 li ka abeloa ho CH, O=C=O, C=O, C=C, le CO otlollang vibrations, ka ho latellana.Hoa tsebahala hore lihlopha tse sebetsang tsa oksijene C=O le CO li ka sebetsa e le litsi tse sebetsang bakeng sa karabelo ea redox ea vanadium.Ho hlahloba le ho bapisa ho nosetsa ha li-electrode tse peli, litekanyo tsa mahlakore a ho kopana li ile tsa sebelisoa joalokaha ho bontšitsoe setšoantšong sa 5b, c.Electrode ea HWO hang-hang e monya marotholi a metsi, e bontšang superhydrophilicity ka lebaka la lihlopha tse sebetsang tsa OH tse teng.HWO-50% C76 e na le hydrophobic ho feta, e nang le angle ea ho kopana e ka bang 135 ° ka mor'a metsotsoana e 10.Leha ho le joalo, litekanyong tsa electrochemical, electrode ea HWO-50% C76 e ile ea kolobisoa ka ho feletseng ka nako e ka tlaase ho motsotso.Litekanyo tsa boemo ba metsi li lumellana le liphetho tsa XPS le FTIR, tse fanang ka maikutlo a hore lihlopha tse ngata tsa OH holim'a HWO li etsa hore e be hydrophilic haholoanyane.
Lits'ebetso tsa VO2+/VO2+ tsa HWO le HWO-C76 nanocomposites li ile tsa lekoa 'me ho ne ho lebelletsoe hore HWO e tla hatella phetoho ea khase ea chlorine e etsahalang nakong ea karabelo ea VO2+/VO2+ ka li-acid tse tsoakiloeng, athe C76 e tla tsoela pele ho susumetsa VO2+/ VO2+ e lakatsehang.Li-suspension tsa HWO tse nang le 10%, 30% le 50% C76 li ile tsa sebelisoa ho li-electrode tsa UCC tse nang le mojaro o ka bang 2 mg / cm2.
Joalokaha ho bontšitsoe feiga.6, kinetics ea VO2 +/VO2+ karabelo holim'a eleketrode e ile ea hlahlojoa ho sebelisoa CV ka li-electrolyte tsa acidic tse tsoakiloeng.Currents li bontšoa e le I/Ipa ho thusa ho bapisa ΔEp le Ipa/Ipc.Li-catalyst tse sa tšoaneng li fumanoa ka ho toba ho tloha setšoantšong.Lintlha tsa hajoale tsa yuniti ea sebaka li bonts'itsoe ho Figure 2S.Ka feiga.Setšoantšo sa 6a se bontša hore HWO e eketsa hanyenyane lebelo la phetisetso ea elektronike ea VO2 +/VO2+ redox reaction holim'a elektrode holim'a metsi le ho hatella karabelo ea ho iphetola ha chlorine ea parasitic.Leha ho le joalo, C76 e eketsa haholo sekhahla sa phetisetso ea elektrone mme e susumetsa karabelo ea ho iphetola ha chlorine.Ka hona, motsoako o nang le motsoako o nepahetseng oa HWO le C76 o lokela ho ba le ts'ebetso e ntle ka ho fetisisa le bokhoni bo phahameng ka ho fetisisa ba ho thibela karabelo ea chlorine.Ho ile ha fumanoa hore ka mor'a ho eketsa litaba tsa C76, mosebetsi oa electrochemical oa electrode o ile oa ntlafala, joalokaha ho pakoa ke ho fokotseha ha ΔEp le keketseho ea Ipa / Ipc ratio (Letlapa la S3).Sena se boetse se tiisitsoe ke litekanyetso tsa RCT tse ntšitsoeng morerong oa Nyquist setšoantšong sa 6d (tafole S3), moo ho fumanoeng hore litekanyetso tsa RCT li fokotsehile ka litaba tse ntseng li eketseha tsa C76.Liphetho tsena li boetse li lumellana le boithuto ba Lee moo kenyelletso ea mesoporous carbon ho mesoporous WO3 e ntlafalitseng kinetics ea phetisetso ea tefiso ho VO2+/VO2+35.Sena se fana ka maikutlo a hore karabelo e ntle e ka itšetleha haholo ka conductivity ea electrode (C = C bond) 18,24,35,36,37.Ka lebaka la phetoho ea geometry ea khokahanyo pakeng tsa [VO (H2O) 5] 2+ le [VO2 (H2O) 4]+, C76 e ka boela ea fokotsa khatello ea maikutlo ka ho fokotsa matla a lisele.Leha ho le joalo, sena se kanna sa se khonehe ka li-electrode tsa HWO.
(a) Cyclic voltammetric behavior of UCC le HWO-C76 composites tse fapaneng HWO:C76 ratios in VO2+/VO2+ reactions in 0.1 M VOSO4/1 M H2SO4 + 1 M HCl electrolyte (ho ν = 5 mV/s).(b) Randles-Sevchik le (c) Mokhoa oa Nicholson oa VO2+/VO2+ oa ho hakanya katleho ea phallo le ho fumana boleng ba k0 (d).
E ne e se feela hore HWO-50% C76 e ne e bontša hoo e batlang e le ts'ebetso ea electrocatalytic e tšoanang le ea C76 bakeng sa karabelo ea VO2 +/VO2+, empa, ho khahlisang le ho feta, e boetse e hatelletse phetoho ea khase ea chlorine ha e bapisoa le C76, joalo ka ha ho bonts'itsoe setšoantšong.6a, ntle le ho bonts'a semicircle e nyane ho feiga.6g (RCT e tlase).C76 e bontšitse Ipa / Ipc e phahameng e bonahalang ho feta HWO-50% C76 (Letlapa la S3), eseng ka lebaka la ntlafatso ea karabelo e ntlafetseng, empa ka lebaka la ho kopana le tlhōrō ea ho fokotsa chlorine ho 1.2 V ha e bapisoa le SHE.Ts'ebetso e ntle ka ho fetisisa ea HWO-50% C76 e bakoa ke ts'ebelisano lipakeng tsa C76 e qosoang hampe le ts'ebetso e phahameng ea metsi le ts'ebetso ea W-OH ho HWO.Le ha tlhahiso e nyane ea chlorine e tla ntlafatsa ts'ebetso ea ho tjhaja sele e felletseng, kinetics e ntlafalitsoeng e tla eketsa bokhoni ba motlakase o felletseng oa sele.
Ho ea ka equation S1, bakeng sa karabelo ea quasi-reversible (e liehang ho fetisa elektronike) e laoloang ke ho hasana, tlhōrō ea hona joale (IP) e itšetlehile ka palo ea li-electrone (n), sebaka sa electrode (A), coefficient ea phallo (D), palo. ea lielektrone fetisa coefficient (α) le lebelo la ho hlahloba (ν).E le ho ithuta boitšoaro bo laoloang ke ho hasana ha thepa e lekiloeng, kamano pakeng tsa IP le ν1/2 e ile ea raloa 'me ea bontšoa setšoantšong sa 6b.Kaha lisebelisoa tsohle li bonts'a kamano ea mohala, karabelo e laoloa ke ho hasana.Kaha VO2 +/VO2+ reaction ke quasi-reversible, moepa oa mola o itšetlehile ka coefficient ea diffusion le boleng ba α (equation S1).Ka lebaka la coefficient e sa khaotseng ea phallo (≈ 4 × 10–6 cm2/s) 52, phapang ea letsoapo la mola e bontša ka ho toba litekanyetso tse fapaneng tsa α, kahoo litekanyetso tse fapaneng tsa phetisetso ea elektrone sebakeng sa elektrode, ka C76 le HWO -50. % C76, e bonts'ang matsoapo a phahameng ka ho fetisisa (sekhahla se phahameng ka ho fetisisa sa phetisetso ea elektronike).
Matsoapo a tlase-tlase a Warburg (W) a bonts'itsoeng ho Lethathamo la S3 (Fig. 6d) a na le boleng bo haufi le 1 bakeng sa lisebelisoa tsohle, e bonts'ang phallo e phethahetseng ea likaroloana tsa redox le ho netefatsa boitšoaro bo tšoanang ba IP khahlanong le ν1/2 bakeng sa CV.litekanyo .Bakeng sa HWO-50% C76, letsoapo la Warburg le kheloha bonngoeng ho ea ho 1.32, ho fana ka maikutlo a ho kenya letsoho eseng feela ho tsoa ho semi-infinite diffusion ea reactants (VO2+), empa hape le boitšoaro bo ka 'nang ba e-ba mosesaane boitšoarong ba ho hasana ka lebaka la electrode porosity.
Ho tsoela pele ho hlahloba phetoho (tekanyo ea phetisetso ea elektronike) ea VO2 +/VO2+ redox reaction, mokhoa oa Nicholson quasi-reversible reaction o ile oa boela oa sebelisoa ho fumana tekanyo e tloaelehileng ea k041.42.Sena se etsoa ka ho rala paramethara ea kinetic e senang dimensionless Ψ joalo ka ts'ebetso ea ΔEp joalo ka ts'ebetso ea ν−1/2 ho sebelisoa equation ea S2.Letlapa la S4 le bonts'a boleng ba Ψ bakeng sa thepa e 'ngoe le e' ngoe ea elektrode.Rala liphetho (setšoantšo sa 6c) ho fumana k0 × 104 cm/s (e ngotsoeng haufi le mola o mong le o mong le ho hlahisoa ho Lethathamo la S4) u sebelisa equation S3 bakeng sa moepa oa morero ka mong.HWO-50% C76 e fumanoe e e-na le moepa o phahameng ka ho fetisisa (setšoantšo sa 6c) 'me kahoo k0 e phahameng ka ho fetisisa ea 2.47 × 10-4 cm / s.Sena se bolela hore electrode ena e fana ka kinetics e potlakileng ka ho fetisisa e lumellanang le liphello tsa CV le EIS ho Figures 6a le d le Table S3.Ntle le moo, boleng ba k0 le bona bo ile ba fumanoa ho tsoa mererong ea Nyquist (setšoantšo sa 6d) sa Equation S4 ho sebelisoa boleng ba RCT (Letlapa la S3).Liphetho tsena tsa k0 ho tsoa ho EIS li akaretsoa ho Lethathamo la S4 hape li bonts'a hore HWO-50% C76 e bonts'a sekhahla se phahameng sa phetisetso ea elektronike ka lebaka la phello ea synergistic.Leha boleng ba k0 bo fapana ka lebaka la tšimoloho e fapaneng ea mokhoa o mong le o mong, e ntse e bonts'a tatellano e tšoanang ea boholo mme e bonts'a botsitso.
Ho utloisisa ka botlalo li-kinetics tse ntle tse ka finyelloang, ke habohlokoa ho bapisa lisebelisoa tse ntle tsa electrode le li-electrode tsa UCC le TCC tse sa tsitsang.Bakeng sa karabelo ea VO2+/VO2+, HWO-C76 ha e ea bonts'a feela ΔEp e tlase le ho fetoha hantle, empa hape e hatelletse karabelo ea phetoho ea chlorine ea parasitic ha e bapisoa le TCC, joalo ka ha ho bonts'itsoe ke ho theoha ho hoholo ha hona joale ho 1.45 V ha ho bapisoa le ho bona OHA (Feie. 7a).Mabapi le botsitso, re ne re nahana hore HWO-50% C76 e tsitsitse 'meleng hobane catalyst e ne e kopantsoe le PVDF binder ebe e sebelisoa ho li-electrode tsa lesela la carbon.Ha ho bapisoa le 50 mV bakeng sa UCC, HWO-50% C76 e bontšitse phetoho e phahameng ea 44 mV ka mor'a lipotoloho tsa 150 (sekhahla sa ho senyeha ha 0.29 mV / cycle) (Setšoantšo sa 7b).E ka 'na ea se ke ea e-ba phapang e kholo, empa kinetics ea li-electrode tsa UCC e lieha haholo ebile e senya ka baesekele, haholo-holo bakeng sa karabelo ea morao.Le hoja phetoho ea TCC e le molemo haholo ho feta ea UCC, TCC e fumanoe e na le phetoho e kholo ea tlhōrō ea 73 mV ka mor'a lipotoloho tse 150, e ka 'nang ea bakoa ke bongata bo boholo ba chlorine e tsoang holim'a eona.Ho etsa bonnete ba hore catalyst e khomarela hantle holim'a electrode.Joalokaha ho ka bonoa ho li-electrode tsohle tse lekiloeng, esita le tse se nang li-catalyst tse tšehetsoeng li bontša maemo a sa tšoaneng a ho se tsitse ha libaesekele, ho fana ka maikutlo a hore liphetoho tsa karohano ea tlhōrō nakong ea ho palama libaesekele li bakoa ke ho tima thepa ka lebaka la liphetoho tsa lik'hemik'hale ho e-na le karohano ea catalyst.Hape, haeba palo e kholo ea likaroloana tsa catalyst e ne e tla aroloa ho tloha holim'a motlakase, sena se ne se tla lebisa keketseho e kholo ea karohano ea tlhōrō (eseng feela ka 44 mV), kaha substrate (UCC) e batla e sa sebetse bakeng sa VO2 +/VO2 + karabelo ea redox.
Papiso ea CV (a) le botsitso ba karabelo ea redox VO2 +/VO2+ (b) ea lisebelisoa tse ntle tsa electrode mabapi le CCC.Ho electrolyte 0.1 M VOSO4/1 M H2SO4 + 1 M HCl, li-CV kaofela li lekana le ν = 5 mV/s.
Ho eketsa khahleho ea moruo ea theknoloji ea VRFB, ho ntlafatsa le ho utloisisa kinetics ea karabelo ea vanadium redox ho bohlokoa ho fihlela katleho e phahameng ea matla.Li-composites HWO-C76 li ile tsa lokisoa 'me phello ea bona ea electrocatalytic ho karabelo ea VO2+/VO2+ e ile ea ithutoa.HWO e bonts'itse ntlafatso e nyane ea kinetic empa e hatelletse kholo ea chlorine ho li-electrolyte tse kopaneng tsa asiti.Likarolo tse fapaneng tsa HWO: C76 li ile tsa sebelisoa ho ntlafatsa kinetics ea li-electrode tse thehiloeng ho HWO.Ho eketsa litaba tsa C76 ho HWO ho ka ntlafatsa kinetics ea phetisetso ea elektronike ea VO2 +/VO2+ ka electrode e fetotsoeng, eo HWO-50% C76 e leng thepa e ntle ka ho fetisisa hobane e fokotsa ho hanyetsa phetisetso ea tefiso le ho feta ho hatella phetoho ea khase ea chlorine ha e bapisoa le C76.le TCC lia lokolloa.Sena se bakiloe ke phello ea synergistic lipakeng tsa C=C sp2 hybridization, OH le W-OH lihlopha tse sebetsang.Tekanyo ea ho senyeha ha HWO-50% C76 e fumanoe e le 0.29mV / cycle tlas'a libaesekele tse ngata ha UCC le TCC li le 0.33mV / cycle le 0.49mV / cycle ka ho latellana, e leng se etsang hore e be e tsitsitseng haholo ho li-electrolyte tse tsoakiloeng tsa acid.Liphetho tse hlahisitsoeng ka katleho li tsebahatsa lisebelisoa tse phahameng tsa elektrode bakeng sa karabelo ea VO2+/VO2+ ka kinetics e potlakileng le botsitso bo phahameng.Sena se tla eketsa phallo ea motlakase, ka ho etsa joalo se ntlafatse ts'ebetso ea matla a VRFB, ka hona se fokotsa litšenyehelo tsa khoebo ea eona ea nako e tlang.
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